However, austenitic stainless steels are susceptible to stress corrosion cracking scc after welding. The sensitization and stress corrosion cracking of nitrogen. Stress corrosion cracking of sensitized austenitic stainless steels. Ferritic stainless steels such as the 430 series, 29cr alloys, and xm alloys all can be tested by the astm a763 methods to find sensitization. A general selection guide for ferritic alloys is given in the a. Sensitization, intergranular attacic, stress corrosion. Deterioration by clscc can lead to failures that have the potential to release stored energy andor hazardous substances. Astm a 736 sensitization testing of ferritic stainless steel. Sensitization promotes stress corrosion cracking failure in some stainless. An overview of sensitization dynamics in ferritic stainless. Correlation between the degree of sensitization and stress. Continuous cooling sensitization and its evaluation in. Polythionic acid stress corrosion cracking deterioration. In the welded condition many stainless steels are susceptible to rapid intergranular corrosion or stress corrosion cracking.
Healing can be achieved by holding the material at 1100 1200 f for several hours. Intermetallics segregation at grain boundaries in aluminum alloys also causes intergranular corrosion but with a different name. The sensitization temperature of ferritic stainless steel is above 900 c, and annealing at 700800 c can eliminate the tendency of intergranular corrosion. Stressed sensitized 304,316 and 321 stainless steel have been selected and subjected to various environments that included polythionic acid, sour solution and.
Several models have been proposed to explain the sensitization of stainless steel. The isothermal timetemperaturesensitization tts diagrams of two nitrogen containing austenitictype stainless steels ss namely 316 lnb 0. Intergranular corrosion induced by environmental stresses is termed stress corrosion cracking. Intergranular stress corrosion cracking igscc of austenitic stainless steel has been an important concern in nuclear power plants for many years. Stress corrosion cracking scc is the growth of crack formation in a corrosive environment. Exposure of the austenitic stainless steel piping or equipment to moisture and air can lead to a potential for this type of cracking if the ss is sensitized. Austenitic stainless steels are widely used in hydroprocessing units. Certain alloys, when exposed to a temperature characterized as a sensitizing temperature, become particularly susceptible to intergranular corrosion. Stresscorrosion cracking of sensitized type 304 stainless steel in. For the specimen solutiontreated at 73 k, the scc drastically occured by the. The mechanism of stress corrosion cracking in sensitized.
Testing sensitization and predicting susceptibility to intergranular corrosion and intergranular stress corrosion cracking in austenitic stainless steels v. Effects of marine environments on stress corrosion cracking of austenitic stainless steels 1011820 effective december 6, 2006, this report has been made publicly available in accordance with section 734. Correlation between the degree of sensitization and stress corrosion. This causes the steel or alloy to become susceptible to intergranular corrosion or intergranular stress corrosion cracking scc.
Stress corrosion cracking of sensitized austenitic stainless steels in. Lower carbon, means fewer carbides to deplete the chromium. Stress corrosion cracking the alloys 321 and 347 austenitic stainless steel tubing are susceptible to stress corrosion cracking scc in halides similar to alloy 304 stainless steel. Sensitization, intergranular attack, stress corrosion. Failure analysis of corrosion on stainless steel fasteners. Typically the first line of protection is to use an l grade low carbon stainless steel andor filler metal e.
Moreover, hydrogen also plays an important role in scc. Figure 1 shows the cracking that occurred on a 6mo super austenitic stainless steel n08367 exposed to 0. It is believed that this occurs because the chromium content immediately adjacent to the carbide may be below that required for the stainless steel alloy. Inter granular corrosion can be detected by ultrasonic and eddy current methods. In asian countries, the interim storage canisters are planned to be located near the coastline, thus, the canister will face the problems of corrosionstress corrosion in the saline atmosphere with a maximum surface temperature below 180 c. This oxide layer is referred to as a passive layer since it renders the surface.
Chloride stress corrosion cracking of an austenitic. Effects of marine environments on stress corrosion cracking. Pascc is just one type of intergranular corrosion that affects sensitized stainless steels. Kain 1 materials science division, bhabha atomic research centre, trombay, mumbai 400 085, india. The commonly used types of stainless steels, 304304h and 316316h are particularly susceptible, whereas the stabilized grades like 3247 and low carbon grades 304l316l are much less susceptible. However, its relatively high carbon content increases the susceptibility to sensitization and subsequent stress corrosion cracking. Deterioration by clscc can lead to failures that have the potential to release stored energy and or hazardous substances. Highnickel alloys abrass aluminum alloys titanium alloys magnesium alloys zirconium alloys environment hot nitrate, hydroxide, and carbonatebicarbonate solutions. Hydrogen embrittlement cracking of superduplex steel twi. Sensitization, intergranular attacic, stress corrosion cracicing, and. Sensitization is the condition where chromium carbide precipitation at the grain boundaries from a heating process, e. The effects of rolling and sensitization treatments on the.
Stainless steel is known for its corrosion resistance in many environments in which carbon and low alloy tool steels would corrode. Sensitization is generally believed to promote stress corrosion cracking failure in some ferritic stainless steels 8, 9. Corrosion of stainless steel by hot caustic research using solutions of chemically pure caustic sodium hydroxide naoh led to the development of a diagram that attempts to delineate the param eters of concentration and tem perature governing stress corrosion cracking scc of type. Austenitic stainless steel 304h is extensively used in the super heater tubes of power boiler due to its superior mechanical properties at elevated temperatures. Sensitization refers to the precipitation of carbides at grain boundaries in a stainless steel or alloy, causing the alloy to be susceptible to intergranular corrosion. Cracking in the heat affected zone of stainless steel piping due to chromium depletion and chromium carbide formation at the grain boundaries was early a problem for many plants. Resistance to corrosion stainless steel tubing manufacturer. In asian countries, the interim storage canisters are planned to be located near the coastline, thus, the canister will face the problems of corrosion stress corrosion in the saline atmosphere with a maximum surface temperature below 180 c. Sensitization happens when ss steel is heated at temperatures between 425c 815c. Intergranular and transgranular stress corrosion cracking of the aisi 316l stainless steel at polythionic acid environment 8. It results from chromium depletion in the vicinity of carbides precipitated at grain boundaries. Aisi 304l stainless steel ss is used for building dry storage canister for the spent fuel produced in nuclear power plants. The epr test has found wide use as a means to provide a numerical level of sensitization in studies of the effects of sensitization on intergranular corrosion and intergranular stress corrosion cracking behavior. Stress corrosion cracking of sus 304 stainless steel in.
The austenitic stainless steel also exhibited partial sensitization, due to improper annealing, which led to localized corrosion at or near the grain boundaries. The essence of sensitization is that the rate of attack of austenitic stainless steels under intergranular attack iga or stresscorrosion cracking scc conditions. This results because of their similarity in nickel content. Austenitic stainless steels always failure in intergranular corrosion, stress corrosion cracking and their synthesis. Sensitization and stabilization of type 409 ferritic. For example, chloride stress corrosion cracking of austenitic stainless steel has been experienced in hotwater jacketed pipes carrying molten chocolate in the food industry. The typical crack morphology for chloride stress corrosion cracking consists of branched transgranular cracks. At this condition, carbides of chromium are formed near grain boundaries. This work is concerned with investigation of the sensitization and stress corrosion cracking scc of austenitic stainless steel grade 304h. Research stress corrosion cracking testing of nonsensitised.
In sensitized type 304 stainless steel the transition of the cracking mode from transgranular to intergranular was often observed, however, the transition in the opposite direction was not observed. Standard test method for electrochemical reactivation epr. However, with enough heat or time sensitization can still occur in the l grades. Sensitization refers to the precipitation of carbides at grain boundaries in a stainless steel or alloy, causing the steel or alloy to be. It can lead to unexpected sudden failure of normally ductile metal alloys subjected to a tensile stress, especially at elevated temperature.
Chloride stress corrosion cracking of an austenitic stainless. The precipitation occurs because the carbides are insoluble at these temperatures. Austenitic stainless steels find wide applications in industry due to their good weldability, superior corrosion resistance and creep resistance. Polythionic acids form from sulfide scales exposed to oxygen and water in the stainless steel that are sensitized which can occur in most stainlesssteel tube materials after exposures to temperatures in excess of 700f to. Quantitative modeling of sensitization development in. Generally, practice w is used as a screening test while x, y, and z are each used for various ferritic stainless stainless steel alloys to evaluate sensitization more quantitatively. The austenitic stainless steel tubes in these services can be susceptible to polythionic acid stress corrosion cracking. Intergranular corrosion stainless steel tubing manufacturer. Stress corrosion cracking scc in type 316l stainless steel local stress relief should be approached with caution as the temperature gradients may result in stresses developing outside the heated band. Abstractniobium stabilized 20cr25ni stainless steel is used for nuclear fuel cladding in the uks fleet of advanced gas cooled reactors agrs. Stress corrosion cracking scc 1 is a common and dangerous form of cracking that occurs due to the combination of stress and corrosive environments. Because the chromium is the primary alloying element that makes stainless steel corrosion resistant, the chromiumdepleted regions are susceptible to preferential corrosion attack. Precold work for stainless steel accelerates scc at less than 10% reduction.
The corrosion resistance is a result of a very thin about 5 nanometers oxide layer on the steels surface. Stabilization heat treatment of austenitic stainless steel. Typically the first line of protection is to use an l grade low carbon stainless steel and or filler metal e. Sensitization of austenitic stainless steels intergranular stress corrosion cracking igscc of austenitic stainless steels, usually aisi 304 steel, is a serious problem in boiling water reactors bwr. Effects of sensitization and hydrogen on stress corrosion cracking of 188 type stainless steel 304 and 304l were investigated in this paper. Testing sensitization and predicting susceptibility to. Intermetallics segregation at grain boundaries in aluminum alloys also causes intergranular corrosion but with a different name exfoliation. Stainless steels are more resistant to general corrosion compared with carbon steel. Intergranular stress corrosion cracking behavior of types 308. With regard to the safe temperature for carbon steel, the reader should look at the curve in figure 1. Intergranular corrosion ssina ssina specialty steel. Methods to avoid material sensitization during welding for. Krishnan k n, knott j f and strangwood m, hydrogen embrittlement during corrosion fatigue of duplex stainless steel, hydrogen effects in materials, p689 the minerals and metals society, 1996.
Intergranular corrosion and intergranular stress corrosion cracking are the two localized corrosion mechanisms that are of concern to the typical applications of austenitic stainless steels in. But the steels, when subjected to temperatures in the range 450 900 oc, are prone to intergranular corrosion and intergranular stress corrosion cracking as a result of sensitization. The sensitization behavior of types 308 and 316 stainless steel weld metals as internal overlays for reactor pressure vessels rpvs was studied with respect to the effects of postweld heat treatment pwht at about 600 c during rpv fabrication and lowtemperature aging during operation. Intergranular stress corrosion cracking behavior of types. Astm a 763 sensitization testing of ferritic steels although its more commonly thought of with austenitic stainless steels, sensitization can also affect the ferritic stainless steels. In asian countries, the interim storage canisters are planned to be located near the coastline, thus, the canister will face the problems of corrosionstress corrosion in the saline atmosphere with a maximum surface temperature. From this attack, branching stress corrosion cracks progressed. The astm standard for a376 and a 312 gives this treatment for the stabilzed grade austenitic stainless steels as a supplementary requirement without. Characterization of the stress corrosion cracking behavior. Chloride stress corrosion cracking in austenitic stainless. Effects of sensitization and hydrogen on stress corrosion.
Then, the stress corrosion cracking mechanism for various materials in conditions that are susceptible is discussed in detail. It is associated with the simultaneous presence of a number of factors. Effects of solution temperature and sensitization time on the stress corrosion cracking scc cf type 304 stainless steel were studied in high temperature water at 562 k containing dissolved oxygen of 8 ppm, using the slow strain rate testing ssrt technique at the strain rate of 4. It is difficult to control the temperature, while changing pipe material or eliminating residual stresses associated with welding and forming the pipework is costly and. They can be subject to polythionic acid stress corrosion cracking during shut down. Gooch t g and leonard a j, hydrogen cracking of ferriticaustenitic stainless steel weld metal, duplex america 2000, p345 kci publishing, 2000. The commonly used types of stainless steels, 304304h and 316316h are particularly susceptible, whereas the stabilized grades like 3247 and low carbon grades 304l316l are.
In this chapter, the conditions for the occurrence of scc are first introduced. Sensitization in stainless steels is caused by chromium depleted zones near grain boundaries which can lead to intergranular corrosion and intergranular stress corrosion cracking in service. The high resistance of the stabilized alloy 321 and alloy 347 stainless steel to sensitization and intergranular corrosion is illustrated by data for the 321 alloy in the coppercopper sulfate 16% sulfuric acid test astm a262, practice e below. Chloride stress corrosion cracking in austenitic stainless steel. Effects of marine environments on stress corrosion. The stress corrosion of two aisi 304 and one aisi 316 stainless steels, fully austenitized and at two different sensitization degrees, has been studied in nacl. Even dough sensitization and hydrogen embrittlement failures can be classified as stress corrosion cracking, they are so distinctive and important a form of corrosion that deserve to be treated in a section of their own. Stress corrosion cracking of sensitized type 304 stainless. A thermal stabilization treatment at 899 900 deg c for two hours is specified for increasing the corrosion resistance to intergranular corrosion and polythionic acid stress corrosion cracking. The stress corrosion cracking of a sensitized type 304 stainless steel has been studied at room temperature using controlled potentials and two concentrati. The cladding can have chromiumdepleted grain boundaries as a consequence of irradiation in a reactor core, rendering a small proportion of cladding susceptible to intergranular stress corrosion cracking in cooling.
Testing sensitization and predicting susceptibilityto. Stresses can occur for a variety of reasons, including welding, physical damage, forming, machining, grinding, heat treatment, and operating stresses. Scc is highly chemically specific in that certain alloys are likely to undergo scc only when exposed to a small number of chemical environments. For the study, a criterion for the rate of intergranular corrosion igc for detecting the susceptibility. If sensitization has occurred in a ferritic stainless steel, the condition can be healed by back diffusing chromium into the depleted regions. Chemically stabilized austenitic stainless steels such as tp321 and tp347 are widely used for hydrotreater and hydrocracker in complex refinery, because of their resistance to high temperature corrosion by desulfurizing process. The purpose of this paper is to investigate stress corrosion cracking scc for 304, 316, and 321 stainless steels in petroleum. Oct 29, 2017 sensitization is the loss of alloy integrity. For the study, a criterion for the rate of intergranular corrosion igc for. The use of a free machining stainless steel resulted in localized galvanic cells or corrosion at inclusions. The stress corrosion cracking of sensitized austenitic stainless steels. Astm a 763 sensitization testing of ferritic steels. Stress corrosion cracking of sus 304 stainless steel in high.
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